Professor Mark Humphrey
BSc(Hons) PhD DSc (Adel.) DUniv (h.c.) (Rennes) MAE CChem FRSC FRACI
Professor
ANU College of Science
Areas of expertise
- Structural Chemistry And Spectroscopy 030606
- Organometallic Chemistry 039904
- Organic Chemical Synthesis 030503
- Quantum Chemistry 030701
- Materials Engineering 0912
- Inorganic Chemistry 0302
- Transition Metal Chemistry 030207
- Optical Properties Of Materials 030303
- Nonlinear Optics And Spectroscopy 020503
Biography
Mark Humphrey received PhD (1987) and DSc (2002) degrees from the University of Adelaide and a DUniv (h.c.) from the Université Rennes 1, France (2019). He held positions at Universität Würzburg, Germany (1987-1989), the University of Illinois, USA (1989-1990), and the University of New England (1990-1994), before being appointed to the ANU as Lecturer in 1994 and being promoted to Senior Lecturer (1995), Reader (1998) and Professor (2003). He has been elected to the European Academy of Sciences (2020) and the Academia Europaea (2021).
He has been awarded fellowships by the Alexander von Humboldt Foundation (Germany, 1987), CNRS (France, 1988) (not activated), Telstra (Australian Telecom) (1991), the Royal Australian Chemical Institute (1997), the Science and Technology Agency (Japan, 2001), the Royal Society of Chemistry (UK, 2002), and the Japan Society for the Promotion of Science (2009), as well as the Gritton Fellowship (University of Sydney, 1990) (not activated), the inaugural RACI Organometallic Award (1998), the RACI Inorganic Award (Burrows Award) (2008), the RACI H.G. Smith Memorial Medal (2010), the RACI A.E. Leighton Memorial Medal (2017), and the David Syme Research Prize (2001), an ARC Australian Research Fellowship (1994), ARC Senior Research Fellowship (1999), and two ARC Australian Professorial Fellowships (2004, 2009), an International Distinguished Professorship (Jiangsu Province, 2011), and a Chinese Government 1000 Talents Award (2012) (not activated). He has been Professeur Invité at the Université Rennes I (France) on several occasions (2007, 2015, 2016, 2019), Visiting Professor at the KU Leuven (Belgium) (2006), and was an Honorary Professor at Nanjing University of Science and Technology (2007), Anniversary Professor at Jiangsu University (2007), and Guest Professor at Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences (2015). He was Associate Director (Research) of the RSC, ANU (2011-2013), a former Chair of the Inorganic Division of the Royal Australian Chemical Institute (2010-2013), and a former President of the ACT Branch of the Royal Australian Chemical Institute (1999-2001). He was the Australian Director of the Australian Government Department of Innovation, Industry, Science and Research-funded Australia-China Joint Research Centre for Functional Molecular Materials (2009-2011), and a CNRS (France)-funded CNRS International Associated Laboratory (2017-2020). He was a member of the Australian Research Council College of Experts (2016-2018) and a member of two ARC Excellence in Research for Australia Research Evaluation Committees (2012, 2018).
Researcher's projects
Please contact Professor Humphrey for specific information on current and previous research projects.
Current student projects
Please contact Professor Humphrey for specific information on current student projects.
Past student projects
Please contact Professor Humphrey for specific information on past student projects.
Publications
- Zhang, X, Shi, L, Fox, M et al. 2021, 'Nonlinear optical properties of meso-Tetra(fluorenyl)porphyrins peripherally functionalized with one to four ruthenium alkynyl substituents', Dyes and Pigments, vol. 188.
- Fu, J, Dong, J, Si, R et al. 2021, 'Synergistic Effects for Enhanced Catalysis in a Dual Single-Atom Catalyst', ACS Catalysis, vol. 11, no. 4, pp. 1952-1961.
- Yang, G, Jiang, X, Wu, C et al. 2021, 'Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence', Dalton Transactions, vol. 50, no. 10, pp. 3568-3576.
- Alsaeedi, M, Babgi, B, Abdellatif, M et al. 2021, 'DNA-Binding Capabilities and Anticancer Activities of Ruthenium(II) Cymene Complexes with (Poly)cyclic Aromatic Diamine Ligands', Molecules, vol. 26, no. 1.
- Li, H, Hou, R, Sun, Y et al. 2021, 'Switching the Nonparametric Optical Nonlinearity of Tungsten Oxide by Electrical Modulation', Advanced Optical Materials, vol. 9, no. 12.
- Lu, Y, Jiang, X, Wu, C et al. 2021, 'Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution', Inorganic Chemistry, vol. 60, no. 8, pp. 5851-5859.
- Wu, C, Jiang, X, Wang, Z et al. 2021, 'UV Solar-Blind-Region Phase-Matchable Optical Nonlinearity and Anisotropy in a π-Conjugated Cation-Containing Phosphate', Angewandte Chemie International Edition, vol. 60, pp. 1-6.
- Wu, C, Jiang, X, Lin, L et al. 2021, 'In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na5(SeO4)(HSeO4)3(H2O)2', Inorganic Chemistry Frontiers, vol. 8, no. 12, pp. 3141-3148.
- Alsaedi, S, Babgi, B, Abdellatif, M et al. 2021, 'Dna-binding and cytotoxicity of copper(I) complexes containing functionalized dipyridylphenazine ligands', Pharmaceutics, vol. 13, no. 5.
- Xu, Q, Jiang, X, Wu, C et al. 2021, 'Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap', Journal of Materials Chemistry C, vol. 9, no. 15, pp. 5124-5131.
- Wu, C, Wu, T, Jiang, X et al. 2021, 'Large Second-Harmonic Response and Giant Birefringence of CeF2(SO4) Induced by Highly Polarizable Polyhedra', Journal of the American Chemical Society, vol. 143, no. 11, pp. 4138-4142.
- Lin, L, Jiang, X, Wu, C et al. 2021, 'CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation', Chemistry of Materials, vol. 33, no. 14, pp. 5555-5562.
- Lin, L, Jiang, X, Wu, C et al. 2021, 'First chiral fluorinated lead vanadate selenite Pb2(V2O4F)(VO2)(SeO3)3 with five asymmetric motifs and large optical properties', Dalton Transactions, vol. 50, no. 21, pp. 7238-7245.
- Alsaedi, S, Babgi, B, Abdellatif, M et al. 2021, 'Effect of Net Charge on DNA-Binding, Protein-Binding and Anticancer Properties of Copper(I) Phosphine-Diimine Complexes', Journal of Inorganic and Organometallic Polymers and Materials, vol. 31, pp. 3943-3952.
- Wu, T, Jiang, X, Wu, C et al. 2021, 'From Ce(IO3)(4) to CeF2(IO3)(2): fluorinated homovalent substitution simultaneously enhances SHG response and bandgap for mid-infrared nonlinear optics', Journal of Materials Chemistry C, vol. 9, pp. 8987ââ¬â8993.
- Hu, Y, Wu, C, Jiang, X et al. 2021, 'Giant Second-Harmonic Generation Response and Large Band Gap in the Partially Fluorinated Mid-Infrared Oxide RbTeMo2O8F', Journal of the American Chemical Society, vol. 143, no. 32, pp. 12455-12459.
- Fu, L, Ye, J, Li, H et al. 2021, 'Strong near-infrared and ultrafast femtosecond nonlinearities of a covalently-linked triply-fused porphyrin dimer-SWCNT nanohybrid', Nano Research, vol. 15, no. 2, pp. 1355-1365.
- Hu, Y, Jiang, X, Wu, C et al. 2021, 'A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation', Chemistry of Materials, vol. 33, no. 14, pp. 5700-5708.
- Wu, C, Jiang, X, Lin, L et al. 2021, 'A Congruent-Melting Mid-Infrared Nonlinear Optical Vanadate Exhibiting Strong Second-Harmonic Generation', Angewandte Chemie International Edition, vol. 60, no. 41, pp. 22447-22453.
- Ripoche, N, Betou, M, Philippe, C et al. 2021, 'Two-photon absorption properties of multipolar triarylamino/tosylamido 1,1,4,4-tetracyanobutadienes', Physical Chemistry Chemical Physics, vol. 23, no. 39, pp. 22283-22297.
- Wu, C, Jiang, X, Lin, L et al. 2021, 'Strong SHG Responses in a Beryllium-Free Deep-UV-Transparent Hydroxyborate via Covalent Bond Modification', Angewandte Chemie International Edition, vol. 60, no. 52, pp. 27151-27157.
- Wu, T, Jiang, X, Zhang, Y et al. 2021, 'From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence', Chemistry of Materials, vol. 33, no. 23, pp. 9317-9325.
- Wu, C, Jiang, X, Hu, Y et al. 2021, 'A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep-UV Transparency', Angewandte Chemie International Edition, vol. 61, no. 6.
- Xia, Y, Du, Y, Xiang, Q et al. 2021, 'Highly Efficient Room-Temperature Phosphorescent Materials with a Heavy-Atom Effect of Bromine', New Journal of Chemistry, vol. 45, no. 11, pp. 4930-4933.
- Hou, R, Li, H, Sun, Y et al. 2021, 'Electrical Tuning of the Fifth-Order Optical Nonlinearity of Antimony-Doped Tin Oxide', Advanced Optical Materials, vol. 9, no. 2, pp. 2001357-2001357.
- Wu, C, Jiang, X, Wang, Z et al. 2021, 'Giant Optical Anisotropy in the UV-Transparent 2D Nonlinear Optical Material Sc(IO3)2(NO3)', Angewandte Chemie International Edition, vol. 60, no. 7, pp. 3464-3468.
- Xia, Y, Zhang, M, Ren, S et al. 2020, '6,12-Dihydro-6,12-diboradibenzo[def,mno]chrysene: A Doubly Boron-Doped Polycyclic Aromatic Hydrocarbon for Organic Light Emitting Diodes by a One-Pot Synthesis', Organic Letters, vol. 22, no. 20, pp. 7942â7946.
- Wu, C, Li, L, Lin, L et al. 2020, 'Gd(NO3)(Se2O5)3H2O: A nitrate-selenite nonlinear optical material with a short ultraviolet cutoff edge', Dalton Transactions, vol. 49, no. 10, pp. 3253-3259.
- Lin, L, Jiang, X, Wu, C et al. 2020, 'Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation', ACS Applied Materials & Interfaces, vol. 12, no. 44, pp. 49812-49821.
- Alsaeedi, M, Babgi, B, Hussien, M et al. 2020, 'DNA-binding and anticancer activity of binuclear gold(I) alkynyl complexes with a phenanthrenyl bridging ligand', Molecules, vol. 25, no. 5, pp. -.
- Quintana Lopetegui, C, Cifuentes, M & Humphrey, M 2020, 'Transition metal complex/gold nanoparticle hybrid materials', Chemical Society Reviews, vol. 49, no. 8, pp. 2316-2341.
- Wu, C, Li, L, Lin, L et al. 2020, 'Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution', Chemistry of Materials, vol. 32, no. 7, pp. 3043-3053.
- Wang, T, Wu, C, Lin, L et al. 2020, 'Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)(2)(H2O)(2) and AGa(2)P(2)O(7)(OH)(3)(H2O) (A = K, Rb)', Journal of Solid State Chemistry, vol. 288, pp. 1-10.
- Kubicki, J, Lorenc, M, Cochelin, P et al. 2020, 'Nitro End Groups: Remarkable Vibrational Reporters for Charge Transfer in the Excited States of Oligo(p-phenyleneethynylene)-Bridged Donor-Acceptor Dyads', Journal of Physical Chemistry C, vol. 124, no. 18, pp. 9755-9764.
- Sun, Y, Li, H, Hou, R et al. 2020, 'Realizing Saturable Absorption and Reverse Saturable Absorption in a PEDOT:PSS Film via Electrical Modulation', ACS Applied Materials and Interfaces, vol. 12, no. 43, pp. 48982-48990.
- Wu, C, Jiang, X, Lin, L et al. 2020, 'AGa3F6(SeO3)2(A = Rb, Cs): A new type of phase-matchable hexagonal tungsten oxide material with strong second-harmonic generation responses', Chemistry of Materials, vol. 32, no. 16, pp. 6906-6915.
- Rabouel, I, Richy, N, Amar, A et al. 2020, '1,3,5-Triaryl-1,3,5-Triazinane-2,4,6-Trithiones: Synthesis, Electronic Structure and Linear Optical Properties', Molecules, vol. 25, no. 22, pp. 1-17.
- Lin, L, Li, L, Wu, C et al. 2020, 'Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance', Inorganic Chemistry Frontiers, vol. 7, no. 15, pp. 2736-2746.
- Quintana Lopetegui, C, Morshedi, m, Du, J et al. 2020, 'Hybrids of gold nanoparticles and oligo(p-phenyleneethynylene)s end-functionalized with alkynylruthenium groups: Outstanding two-photon absorption in the second biological window', Nano Research, vol. 13, no. 10, pp. 2755-2762.
- Babgi, B, Mashat, K, Abdellattif, M et al. 2020, 'Synthesis, structures, DNA-binding, cytotoxicity and molecular docking of CuBr(PPh3)(diimine)', Polyhedron, vol. 192, pp. 1-9.
- Qui, S, Morshedi, M, Kodikara, M et al. 2020, 'Organometallic complexes for nonlinear optics.66. Synthesis and quadratic nonlinear optical studies of trans-[Ru{C=C{2,5-C4H2S-( E )-CH=CH}n-2,5-C4H2S(NO2 )}Cl(dppe)2](n1/40-2)', Journal of Organometallic Chemistry, vol. 919, no. 121306, pp. 1-10.
- Quintana Lopetegui, C, Morshedi, M, Wang, H et al 2019, 'Exceptional Two-Photon Absorption in Alkynylruthenium-Gold Nanoparticle Hybrids', Nano Letters, vol. 19, no. 2, pp. 756-760.
- Zhang, J, Liu, Y, Feng, J et al 2019, 'Decanuclear Cluster-Based Metal-Organic Framework with a (3,11)-Connected Topology and Highly Sensitive 2,4,6-Trinitrophenol Detection', Inorganic Chemistry, vol. 58, no. 15, pp. 9749-9755.
- Qian, J, Yoshikawa, H, Hu, J et al 2019, 'Auxiliary ligand-induced structural diversities of octacyanometalate-based heterobimetallic coordination polymers towards diverse magnetic properties', Dalton Transactions, vol. 48, no. 22, pp. 7666-7676.
- Jiang, P, Wang, Z, Moxey, G et al 2019, 'Syntheses and quadratic nonlinear optical properties of 2,7-fluorenylene- and 1,4-phenylene-functionalized o-carboranes', Dalton Transactions, vol. 48, no. 33, pp. 12549-12559.
- Qian, J, Yoshikawa, H, Humphrey, M et al 2019, 'In situ formed [M(CN)(9)] (M = W, Mo) as a building block for the construction of two nona-cyanometalate-bridged heterometallic coordination polymers', CrystEngComm, vol. 21, no. 29, pp. 4363-4372.
- Dong, W, Cortie, D, Lu, T et al 2019, 'Collective nonlinear electric polarization: Via defect-driven local symmetry breaking', Materials Horizons, vol. 6, no. 8, pp. 1717-1725.
- Yang, G, Li, L, Wu, C et al 2019, 'Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region', Inorganic Chemistry, vol. 58, no. 19, pp. 12582-12589.
- Wu, C, Lin, L, Jiang, X et al 2019, 'K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold', Chemistry of Materials, vol. 31, no. 08974756, pp. 10100-10108.
- Al-Rashdi, K, Babgi, B, Sahin, C et al 2018, 'Diamines as auxiliary ligands for tuning photophysical and electrochemical properties of Ruthenium(II) polypyridyl complexes', Journal of Molecular Structure, vol. 1158, pp. 197-204pp.
- Kodikara, M, Stranger, R & Humphrey, M 2018, 'Long-Range Corrected DFT Calculations of First Hyperpolarizabilities and Excitation Energies of Metal Alkynyl Complexes', ChemPhysChem, vol. 19, no. 12, pp. 1537-1546.
- Triadon, A, Grelaud, G, Richy, N et al 2018, 'Linear and Third-Order Nonlinear Optical Properties of Fe(?5-C5Me5)(?2-dppe)- and trans-Ru(?2-dppe)2-Alkynyl Complexes Containing 2-Fluorenyl End Groups', Organometallics, vol. 37, no. 14, pp. 2245-2262.
- Mai, H, Lu, T, Li, Q et al. 2018, 'Photovoltaic Effect of a Ferroelectric-Luminescent Heterostructure under Infrared Light Illumination', ACS Applied Materials and Interfaces, vol. 10, no. 35, pp. 29786-29794.
- Babgi, B, Kodikara, M, Morshedi, M et al 2018, 'Linear Optical, Quadratic and Cubic Nonlinear Optical, Electrochemical, and Theoretical Studies of "Rigid-Rod" Bis-Alkynyl Ruthenium Complexes', ChemPlusChem, vol. 83, no. 7, pp. 630-642.
- Junk, P, Humphrey, M & Koutsantonis, G 2018, 'Editorial', Coordination Chemistry Reviews, vol. 375, pp. 1pp.
- Wang, Z, Wang, T, Zhang, C et al 2018, 'N-Donor/Fluorenyl o-Carborane Fluorophores with Strong Crystallization-Induced Emission', ChemPhotoChem, vol. 2, no. 4, pp. 369-379.
- Triadon, A, Ngo Ndimba, A, Richy, N et al. 2018, 'Diphenylamino-substituted tristyryl vs. triphenyl isocyanurates: improved conjugation has minimal impact on two-photon absorption', New Journal of Chemistry, vol. 42, no. 14, pp. 11289-11293.
- Du, J, Kodikara, M, Moxey, G et al 2018, 'Quadratic and cubic hyperpolarizabilities of nitro-phenyl/-naphthalenyl/-anthracenyl alkynyl complexes', Dalton Transactions, vol. 47, no. 13, pp. 4560-4571pp.
- Kodikara, M, Stranger, R & Humphrey, M 2018, 'Computational studies of the nonlinear optical properties of organometallic complexes', Coordination Chemistry Reviews, vol. 375, pp. 389-409pp.
- Merhi, A, Grelaud, G, Morshedi, M et al 2018, 'Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core', Dalton Transactions, vol. 47, no. 32, pp. 11123-11135pp.
- Humphrey, M 2018, 'Ruthenium Alkynyl Complexes in Non-Linear Optics', Australian Journal of Chemistry, vol. 71, no. 10, pp. 731-742pp.
- Morshedi, M, Kodikara, M, Corkery, T et al 2018, 'Quadratic and Cubic Optical Nonlinearities of Y-Shaped and Distorted-H-Shaped Arylalkynylruthenium Complexes', Chemistry, A European Journal, vol. 24, no. 61, pp. 16332-16341.
- Wu, C, Yang, G, Humphrey, M, & Zhang, C, 2018, 'Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals', Coordination Chemistry Reviews, vol. 375, pp. 459-488pp.
- Wang, C, Wu, J, Jiang, K et al 2017, 'Stable Ag nanoclusters-based nano-sensors: Rapid sonochemical synthesis and detecting Pb2+ in living cells', Sensors and Actuators B, vol. 238, pp. 1136-1143.
- Streatfield, S, Pradels, C, Ndimba, A et al 2017, 'Electronic Absorption, Emission and Two-PhotonAbsorption Properties of Some Functional1,3,5-Triphenylbenzenes', ChemistrySelect, vol. 2, no. 26, pp. 8080-8085.
- Wu, C, Li, L, Song, J et al 2017, 'Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties', Inorganic Chemistry Frontiers, vol. 4, no. 4, pp. 692-700.
- Fu, J, Randles, M, Moxey, G et al. 2017, 'Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo3Ir3(μ4-η2-CO)(μ3-CO)(CO)10(η5-C5H5)3 and Mo3RhIr3(μ-CO)4(CO)7(η5-C5H5)3(η5-C5Me5)', Journal of Organometallic Chemistry, vol. 829, pp. 66-70pp.
- Randles, M, Cifuentes, M, Moxey, G et al 2017, 'High-nuclearity ruthenium carbonyl cluster chemistry. 9. Ligand substitution at decaruthenium carbonyl clusters', Journal of Organometallic Chemistry, pp. -.
- Liu, G, Quintana Lopetegui, C, Wang, G et al 2017, 'Organometallic Complexes for Non-Linear Optics. 59. Syntheses and Optical Properties of Some Octupolar (N-Heterocyclic Carbene)gold Complexes', Australian Journal of Chemistry, vol. 70, no. 1, pp. 79-89.
- Schwich, T, Barlow, A, Cifuentes, M et al 2017, 'Stellar Multi-Photon Absorption Materials: Beyond the Telecommunication Wavelength Band', Chemistry, A European Journal, vol. 23, no. 35, pp. 8395-8399.
- Argouarch, G, Grelaud, G, Roisnel, T et al. 2017, '[Fp*Fc][PF6]: A remarkable non-symmetric dinuclear cation in a very stable mixed-valent state', Journal of Organometallic Chemistry, vol. 847, pp. 218-223.
- Wu, C, Li, L, Song, J et al 2017, 'Facile Syntheses of Ba2[B4O7(OH)2] and Na[B5O7(OH)2](H2O) Borate Salts Exhibiting Nonlinear Optical Activity in the Ultraviolet', Inorganic Chemistry, vol. 56, no. 3, pp. 1340-1348pp..
- Wang, Z, Wang, T, Zhang, C et al 2017, 'Efficient crystallization-induced emission in fluorenyl-tethered carboranes', Physical Chemistry Chemical Physics, vol. 19, no. 20, pp. 12928-12935pp..
- Zhang, M, Fu, L, Ye, J et al 2017, 'Covalent-linked porphyrin/single-walled carbon nanotube nanohybrids: synthesis and influence of porphyrin substituents on nonlinear optical performance', Carbon, vol. 124, pp. 618-629.
- Wu, C, Li, L, Yang, G et al 2017, 'Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na4MB2P3O13 (M = Rb, Cs) exhibiting a second-harmonic generation response', Dalton Transactions, vol. 46, no. 37, pp. 12605-12611.
- Cv, C, huang, Z, Yang, Q et al 2017, 'Ultrafast synthesis of molybdenum carbide nanoparticles for efficient hydrogen generation', Journal of Materials Chemistry A, vol. 5, pp. 22805-22812.
- Wang, Z, Jiang, P, Wang, T et al 2016, 'Blue-shifted emission and enhanced quantum efficiency via pi-bridge elongation in carbazole-carborane dyads', Physical Chemistry Chemical Physics, vol. 18, no. 23, pp. 15719-15726.
- Wang, A, Yu, W, Huang, Z et al 2016, 'Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance', Scientific Reports, vol. 6, no. 23325, pp. 1-12.
- Gao, B, Mazur, L, Morshedi, M et al 2016, 'Exceptionally large two- and three-photon absorption cross-sections by OPV organometalation', Chemical Communications, vol. 52, no. 53, pp. 8301-8304.
- Wei, D, Kodikara, M, Morshedi, M et al 2016, 'Syntheses and Optical Properties of Azo-Functionalized Ruthenium Alkynyl Complexes', ChemPlusChem, vol. 81, no. 7, pp. 621-628.
- Zhang, H, Morshedi, M, Kodikara, M et al 2016, 'Synthesis, Optical, Electrochemical, and Theoretical Studies of Dipolar Ruthenium Alkynyl Complexes with Oligo(phenylenevinylene) Bridges', ChemPlusChem, vol. 81, no. 7, pp. 613-620.
- Jin, L, Xia, H, huang, Z et al 2016, 'Phase separation synthesis of trinickel monophosphide porous hollow nanospheres for efficient hydrogen evolution', Journal of Materials Chemistry, vol. 4, no. 28, pp. 10925-10932.
- Malvolti, F, Rouxel, C, Grelaud, G et al 2016, 'Iron and Ruthenium Alkynyl Complexes with 2-Fluorenyl Groups: Some Linear and Nonlinear Optical Absorption Properties', European Journal of Inorganic Chemistry, vol. 2016, no. 24, pp. 3868-3882.
- Wu, C, Song, J, Li, L et al 2016, 'Alkali metal-alkaline earth metal borate crystal LiBa3(OH)(B9O16)[B(OH)(4)] as a new deep-UV nonlinear optical material', Journal of Materials Chemistry C: materials for optical and electronic devices, vol. 4, no. 35, pp. 8189-8196.
- Wang, A, Song, J, Huang, Z et al 2016, 'Multi-walled carbon nanotubes covalently functionalized by axially coordinated metal-porphyrins: Facile syntheses and temporally dependent optical performance', Nano Research, vol. 9, no. 2, pp. 458-472.
- Fu, J, Moxey, G, Morshedi, m et al. 2016, 'Mixed-metal cluster chemistry. 37. Syntheses, structural, spectroscopic, electrochemical, and optical power limiting studies of tetranuclear molybdenum-iridium clusters', Journal of Organometallic Chemistry, vol. 812, pp. 135-144.
- Zhang, J, Jia, D, Humphrey, M et al 2016, 'Ammonium-crown ether supramolecular cation-templated assembly of an unprecedented heterobicluster-metal coordination polymer with enhanced NLO properties', Chemical Communications, vol. 52, no. 19, pp. 3797-3800.
- Fu, J, Morshedi, m, Moxey, G et al. 2016, 'Dynamic Permutational Isomerism in a closo-Cluster', Chemistry, A European Journal, vol. 22, no. 15, pp. 5128-5132.
- Wang, A, Wang, Y, Yu, W et al 2016, 'TiO2-multi-walled carbon nanotube nanocomposites: Hydrothermal synthesis and temporally-dependent optical properties', RSC Advances, vol. 6, no. 24, pp. 20120-20127.
- Wang, A, Song, J, Jia, D et al 2016, 'Functionalization of reduced graphene oxide with axially-coordinated metal-porphyrins: Facile syntheses and temporally-dependent nonlinear optical properties', Inorganic Chemistry, vol. 3, no. 2, pp. 296-305.
- Wang, C, Lin, H, Xu, Z et al 2016, 'Tunable Carbon-Dot-Based Dual-Emission Fluorescent Nanohybrids for Ratiometric Optical Thermometry in Living Cells', ACS Applied Materials and Interfaces, vol. 8, no. 10, pp. 6621-6628.
- Simpson, P, Watson, L, Barlow, A et al 2016, 'Record multiphoton absorption cross-sections by dendrimer organometalation', Angewandte Chemie International Edition, vol. 55, no. 7, pp. 2387-2391.
- Van Steerteghem, N, Van Cleuvenbergen, S, Ahmad Shah, N et al 2016, 'Investigation of the second hyperpolarizability of Ru-alkynyl complexes by z-scan and nonlinear scattering', Light Manipulating Organic Materials and Devices III, ed. JE Haley, M Eich, J A Schuller and J M Nunzi, SPIE - The International Society for Optical Engineering, Washington DC, pp. 1-10pp.
- Pokladek, Z, Ripoche, N, Betou, M et al. 2016, 'Linear Optical and Third-Order Nonlinear Optical Properties of Some Fluorenyl- and Triarylamine-Containing Tetracyanobutadiene Derivatives', Chemistry, A European Journal, vol. 22, no. 29, pp. 10155-10167.
- Wang, C, Huang, Y, Humphrey, M et al 2016, 'Dual-emitting quantum dot/carbon nanodot-based nanoprobe for selective and sensitive detection of Fe3+ in cells', Analyst, The, vol. 141, no. 14, pp. 4488-4494.
- Rogachev, A, Gushchin, A, Abramov, P et al 2015, 'Binuclear Sulfide Niobium Clusters Coordinated by Diimine Ligands: Synthesis, Structure, Photocatalytic Activity and Optical Limiting Properties', European Journal of Inorganic Chemistry, vol. 2015, no. 17, pp. 2865-2874.
- Chen, Z, Jeffery, C, Morshedi, M et al 2015, 'Syntheses, Electrochemical, Linear Optical, and Cubic Nonlinear Optical Properties of Ruthenium-Alkynyl-Functionalized Oligo(phenylenevinylene) Stars', ChemPlusChem, vol. 80, no. 8, pp. 1329-1340.
- Zhang, J, Wang, C, Wang, Y et al 2015, 'Single cyanide-bridged Mo(W)/S/Cu cluster-based coordination polymers: Reactant- and stoichiometry-dependent syntheses, effective photocatalytic properties', Journal of Solid State Chemistry, vol. 231, pp. 230-238.
- Zhao, H, Simpson, P, Barlow, A et al 2015, 'Syntheses, Spectroscopic, Electrochemical, and Third-Order Nonlinear Optical Studies of a Hybrid Tris{ruthenium(alkynyl)/(2-phenylpyridine)}iridium Complex', Chemistry, A European Journal, vol. 21, no. 33, pp. 11843-11854.
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- Humphrey, M 2004, 'Towards Oligoclusters - Chemistry and Properties', Canadian Chemistry Conference and Exhibition 2004, Conference Organising Committee, unknown.
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- Usher, A, Humphrey, M & Willis, A 2003, 'Mixed-metal cluster chemistry. 24. Isocyanide derivatives of [MoIr3(μ-CO)3(CO)8(η-C5H5)] and [Mo2Ir2(μ-CO)3(CO)7(η-C5H5)2', Journal of Organometallic Chemistry, vol. 678, no. 1-2, pp. 72-81.
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- Lucas, N, Notaras, E, Humphrey, M et al 2003, 'Syntheses, characterization, and optical limiting properties of heterometallic cluster-containing polymers', IUPAC Congress and Conference of the Canadian Society for Chemistry 2003, Conference Organising Committee, unknown.
- Cookson, D, Humphrey, M, Lucas, N et al 2003, 'Transition Metal Cluster Compounds Containing Chalcogenide Ligands', Conference of the Inorganic Chemistry Division of the Royal Australian Chemical Institute (IC 2003), Conference Organising Committee, n/a.
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- Samoc, M, Samoc, A, Luther-Davies, B et al 2003, 'New Trends in the Studies of Third-order Nonlinearities of Organics', International Conference on Frontiers of Polymers and Advanced Materials (ICFPAM 2003), Conference Organising Committee, n/a.
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- Samoc, M & Humphrey, M 2002, 'Nonlinear Optical Properties of Orgaonmetallics: Do They Have Advantages Over Other Nonlinear Materials?', International Symposium on Modern Optics and its Applications (ISMOA 2002), Conference Organising Committee, n/a.
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- Lucas, N, Notaras, E & Humphrey, M 2001, 'W2Ir2(u4-η2-C2Ph2)(u-CO)4(CO)4(η-C5H4Me)2', Acta Crystallographica Section E: Structure Reports Online, vol. E57, pp. m143-m144.
- Lucas, N, Notaras, E & Humphrey, M 2001, 'W2Ir2(CO)10(η5-C5H4Me)2', Acta Crystallographica Section E: Structure Reports Online, vol. E57, pp. m132-m133.
- Notaras, E, Lucas, N, Blitz, J et al. 2001, 'Mixed-metal cluster chemistry. Part 17. Syntheses of WIr3(CO)11(n-C5H4Me) and its reactivity towards diphenylacetylene', Journal of Organometallic Chemistry, vol. 631, no. 1-2, pp. 143-150.
- Hurst, S, Lucas, N, Humphrey, M et al 2001, 'Organometallic Complexes for Nonlinear Optics.XXVI Quadratic Hyperpolarizabilities of Some 4-Methoxytetrafluorophenylalkynyl Gold and Ruthenium Complexes', Australian Journal of Chemistry, vol. 54, pp. 447-452.
- Waterman, S, Lucas, N & Humphrey, M 2001, 'Very Mixed-Metal Carbonyl Clusters', in West,R. Hill,A.F. (ed.), Advances in Organometallic Chemistry, Academic Press, San Diego, California, pp. 47-143.
- Cifuentes, M, Powell, C, Humphrey, M et al. 2001, 'Organometallic complexes for nonlinear optics. 24. Reversible electrochemical switching of nonlinear absorption', Journal of Physical Chemistry A, vol. 105, no. 42, pp. 9625-9627.
- Hurst, S, Cifuentes, M, Morrall, J et al 2001, 'Organometallic Complexes for Nonlinear Optics. 22. Quadratic and Cubic Hyperpolarizabilities of trans-Bis(bidentate phosphine)ruthenium Ï?-Arylvinylidene and Ï?-Arylalkynyl Complexes', Organometallics, vol. 20, no. 22, pp. 4664-4675.
- Mata, J, Peris, E, Llusar, R et al 2001, 'Syntheses, Structures and Nonlinear Optical Properties of Ferrocenyl Complexes with Arylethenyl Substituents', European Journal of Inorganic Chemistry, pp. 2113-2122.
- Notaras, E, Lucas, N & Humphrey, M 2001, 'Communicative Clusters', World Chemistry Congress 2001, ed. World Chemistry Congress 2001, Unknown, Brisbane, Australia.
- Blitz, J, Lucas, N, Notaras, E et al 2001, 'Structural and Spectroelectrochemical Investigations of Organometallic Cluster Compounds', World Chemistry Congress 2001, ed. World Chemistry Congress 2001, Unknown, Brisbane, Australia.
- Humphrey, M, Cifuentes, M, Powell, C et al 2001, 'Reversible Electrochemical Switching of Nonlinear Absorption', World Chemistry Congress 2001, ed. World Chemistry Congress 2001, Unknown, Brisbane, Australia.
- Freydank, A, Samoc, M, Humphrey, M et al. 2001, 'Second-order NLO-active PMMAs bearing phenylene-vinylene chromophores', World Chemistry Congress 2001, ed. World Chemistry Congress 2001, Unknown, Brisbane, Australia.
- Cifuentes, M, Driver, J, Humphrey, M et al. 2000, 'Organometallic complexes for nonlinear optics Part 18. Molecular quadratic and cubic hyperpolarizabilities of aryldiazovinylidene complexes', Journal of Organometallic Chemistry, vol. 607, pp. 72-77.
- Lucas, N, Powell, C & Humphrey, M 2000, 'cis,cis,cis-(Acetato-O,O)bis[1,2-bis(diphenylphosphino)ethane-P,P]ruthenium(II) hexafluorophosphate dimethanol solvate', Acta Crystallographica Section C: Crystal Structure Communications, vol. C56, pp. e392-e393.
- Vicente, J, Chicote, M, Abrisqueta, M et al 2000, 'Syntheses, Structure, and Molecular Cubic Hyperpolarizabilities of Systematically Varied Ethynylgold(I) Complexes', Organometallics, vol. 19, pp. 2968-2974.
- McDonagh, A, Cifuentes, M, Lucas, N et al. 2000, 'Organometallic complexes for nonlinear optics Part 19. Syntheses and molecular quadratic hyperpolarizabilities of indoanilino-alkynyl-ruthenium complexes', Journal of Organometallic Chemistry, vol. 605, pp. 184-192.
- McDonagh, A, Lucas, N, Cifuentes, M et al. 2000, 'Organometallic complexes for nonlinear optics Part 20. Syntheses and molecular quadratic hyperpolarizabilities of alkynyl complexes derived from (E)-4,4-HCCC6H4N=NC6H4NO2', Journal of Organometallic Chemistry, vol. 605, pp. 193-201.
- Delfs, C, Stranger, R, Humphrey, M et al. 2000, 'Trends in back-bonding in the series trans-[M(C�CR)Cl(PH3)4] (M = Fe, Ru, Os; R = H, Ph, C6H4NO2-4)', Journal of Organometallic Chemistry, vol. 607, pp. 208-212.
- McDonagh, A, Cifuentes, M, Humphrey, M et al. 2000, 'Organometallic complexes for nonlinear optics Part 21. Syntheses and quadratic hyperpolarizabilities of alkynyl complexes containing optically active 1,2-bis(methylphenylphosphino)benzene ligands', Journal of Organometallic Chemistry, vol. 610, pp. 71-79.
- Humphrey, M 2000, 'Gold Complexes for Nonlinear Optics', Gold Bulletin, vol. 33, pp. 97-102.
- Bruce, M & Humphrey, M 2000, 'Organo-Transition Metal Cluster Compounds', in Green, M. (ed.), Organometallic Chemistry Volume 28, Royal Society of Chemistry, UK, pp. 275-366.
- Cifuentes, M, Roxburgh, F & Humphrey, M 1999, 'Ruthenium Complexes with h1-Organic Ligands', Journal of Chemical Education, vol. 76, pp. 401-403.
- Waterman, S, Humphrey, M & Hockless, D 1999, 'Mixed-metal cluster chemistry XII: isocyanide derivatives of [CpWIr3(CO)11]; X-ray crystal structure of [CpWIr3(CO)9(CNC6H3Me2-2,6)2]', Journal of Organometallic Chemistry, vol. 579, pp. 75-82.
- Whittall, I, McDonagh, A & Humphrey, M 1999, 'Organometallics in Nonlinear Optics II: Third-Order Nonlinearities and Optical Limiting Studies', Advances in Organometallic Chemistry, vol. 43, pp. 349-405.
- Waterman, S, Humphrey, M & Lee, J 1999, 'Mixed-metal cluster chemistry 15: some bidentate phosphine chemistry of tungsten-iridium clusters', Journal of Organometallic Chemistry, vol. 589, pp. 226-233.
- Waterman, S & Humphrey, M 1999, 'Mixed-Metal Cluster Chemistry. 10. Isomer distribution and ligand fluxionality at CpWIr3(m-CO)3(CO)8-n(PR3)n', Organometallics, vol. 18, pp. 3116-3127.
- Waterman, S, Humphrey, M, Lee, J et al 1999, 'Mixed-Metal Cluster Chemistry. 13. Syntheses, isomer distribution and fluxionality studies of Cp2W2Ir2(m-CO)3(CO)7-n(PR3)n (n = 1-2; R = Ph, Me); X-ray crystal structure of Cp2W2Ir2(m-CO)3(CO)6(PPh3)', Organometallics, vol. 18, pp. 2440-2451.
- Waterman, S & Humphrey, M 1999, 'Mixed-metal cluster chemistry 14: Reaction of [Cp2W2Ir2(CO)10] with trimethylphosphite; X-ray crystal structures of [Cp2W2Ir2(m-CO)3(CO)5{P(OMe)3}2] and two modifications of [CpWIr3(m-CO)3(CO)7{P(OMe)3}]', Journal of Organometallic Chemistry, vol. 582, pp. 310-318.
- Vicente, J, Chicote, M, Gonzalez-Herrero, P et al 1999, 'New 1,1-ethylenedithiolato complexes of thallium(I), gold(I) and gold(III). Syntheses, structure and cubic hyperpolarizabilities.', Inorganic Chemistry, vol. 38, pp. 5018-5026.
- Waterman, S, Humphrey, M & Hockless, D 1999, 'Mixed-metal cluster chemistry. Part 14: reaction of [Cp2W2Ir2(CO)10] with trimethylphosphite; X-ray crystal structures of [Cp2W2Ir2(m-CO)3(CO)5{P(OMe)3}2] and two modifications of [CpWIr3(m-CO)3(CO)7{P(OMe)3}]', Journal of Organometallic Chemistry, vol. 582, pp. 310?318.
- Houbrechts, S, Wada, T, Sasabe, H et al 1999, 'Novel Organometals for Nonlinear Optics: Octopolar Alkynylmetal Complexes,', Nonlinear Optics, vol. 22, pp. 165-168.
- McDonagh, A & Humphrey, M 1999, 'Organometallic Complexes for Nonlinear Optics. 17. Synthesis, Third-Order Optical Nonlinearities and Two-Photon Absorption Cross Section of an Alkynylruthenium Dendrimer', Organometallics, vol. 18, pp. 5195-5197.
- McDonagh, A, Humphrey, M, Samoc, M et al 1999, 'Organometallic Complexes for Nonlinear Optics 16. Second and Third Order Optical Nonlinearities of Octopolar Alkynylruthenium Complexes', Journal of the American Chemical Society, vol. 121, pp. 1405-1406.
Projects and Grants
Grants information is drawn from ARIES. To add or update Projects or Grants information please contact your College Research Office.
- Programmable Organometallics for Spatiotemporal Light Control (Primary Investigator)
- Preparation and catalytic application of Mo-Ir and W-Ir bimetallic cluster catalysts (Secondary Investigator)
- New materials with increased optical nonlinearity and method of determining their parameters (Secondary Investigator)
- Metal-Rich Materials for Optical Limiting (Primary Investigator)
- Ultrafast Optical Nonlinearities in Robust Organometallic Materials (Primary Investigator)
- Multifunctional metal alkynyls for Nonlinear Optics (Primary Investigator)
- Advanced Cluster Materials for Optical Limiting Applications (Primary Investigator)
- A DIFFRACTOMETER FOR SMALL MOLECULE STRUCTURAL ELUCIDATION BY CRYSTALLOGRAPHIC ANALYSIS (Secondary Investigator)
- Multinuclear 700 MHz NMR Spectrometer for Advanced Molecular Analysis (Secondary Investigator)
- Organometallic Chemistry & Molecular Materials (Primary Investigator)
- Hybrid organometallic-coordination complex materials for nonlinear optics (Primary Investigator)
- A tunable femtosecond light source for materials and biological sciences (Primary Investigator)
- Regional Facility for Molecular Characterization and Mapping (Secondary Investigator)
- Organometallic Switches in Nonlinear Optics (Secondary Investigator)
- Joint Research Centre for Functional Molecular Materials (Primary Investigator)
- Advanced Organometallic Materials: Syntheses and Nonlinear Optical Properties (Primary Investigator)
- Metal Alkynyl Materials for Photonics (Primary Investigator)
