Professor Anthony Hill
B.Sc. (Auckland), M.Sc.Hons (Auckland), Dr Rer. Nat. (Bayreuth, Germany), F.R.S.C., F.R.A.C.I., C.Chem., M.R.N.Z.I.C., M. R. S. N. Z.
Synthetic Organometallic and Coordination Chemistry
ANU College of Science
T:
0261258577
Areas of expertise
- Transition Metal Chemistry 030207
- Main Group Metal Chemistry 030204
- Organometallic Chemistry 039904
- Inorganic Chemistry 0302
Publications
- Barnett, H & Hill, A 2021, 'Benzyne addition to a metal-carbon multiple bond', Dalton Transactions, vol. 27, pp. 9383-9387.
- Frogley, B, Hill, A & Kirk, R 2021, 'Heterocyclic arsinocarbynes via tandem transmetallation', Chemical Communications, vol. 57, no. 70, pp. 8770-8773.
- Burt, L & Hill, A 2021, 'Construction of an iminoketenylidene', Chemical Communications, vol. 57, no. 68, pp. 8480-8483.
- Frogley, B, Hill, A & Welsh, S 2021, 'Bimetallic ethynylanthracenyl functionalised carbynes', Chemical Communications, vol. 57, no. 98, pp. 13353-13356.
- Frogley, B, Hill, A & Welsh, S 2021, 'Symmetric and non-symmetric anthracen-diyl bis(alkylidynes)', Dalton Transactions, vol. 50, no. 43, pp. 15502-15523.
- Hill, A & Watson, L 2020, 'A heterobimetallic cumulenic μ-carbido complex', Chemical Communications, vol. 56, no. 15, pp. 2356-2359.
- Manzano, R, Hill, A & Georgelin, R 2020, 'Tetrel and pnictogen functionalised propargylidynes', Chemical Communications, vol. 56, no. 93, pp. 14597-14600.
- Frogley, B & Hill, A 2020, 'Metal coordination to bipyridyl carbynes', Dalton Transactions, vol. 49, no. 10, pp. 3272-3283.
- Barnett, H & Hill, A 2020, 'A Dirhoda-Heterocyclic Carbene', Angewandte Chemie International Edition, vol. 59, no. 11, pp. 4274-4277.
- Frogley, B, Hill, A, Shang, R et al. 2020, 'In Search of Fulminate Analogues: LnM equivalent to CP=NR', Chemistry, A European Journal, vol. 26, pp. 8819-8827.
- Barnett, H & Hill, A 2020, 'Halogenation of A-frame μ-carbido complexes: a diamagnetic rhodium(ii) carbido complex', Chemical Communications, vol. 56, no. 56, pp. 7738-7740.
- Burt, L, Cordiner, R, Hill, A et al. 2020, 'The significance of phosphoniocarbynes in halocarbyne cross-coupling reactions', Chemical Communications, vol. 56, no. 42, pp. 5673-5676.
- Burt, L & Hill, A 2020, 'Heterobimetallic u2-carbido complexes of platinum and tungsten', Dalton Transactions, vol. 49, no. 24, pp. 8143-8161.
- Frogley, B, Hill, A & Watson, L 2020, 'Advances in Transition Metal Seleno- and Tellurocarbonyl Chemistry', Chemistry, A European Journal, vol. 26, no. 56, pp. 12706-12716.
- Barnett, H & Hill, A 2020, 'Dimetalla-heterocyclic carbenes: The interconversion of chalcocarbonyl and carbido ligands', Chemical Communications, vol. 56, pp. 12593-12596.
- Frogley, B & Hill, A 2020, 'Propargylidyne and Pentadiynylidyne Polyfunctionalised Polycyclic Aromatic Hydrocarbons', Chemistry, A European Journal, vol. 26, no. 53, pp. 12125-12128.
- Onn, C, Hill, A & Olding, A 2020, 'Metal coordination of phosphoniocarbynes', Dalton Transactions, vol. 49, no. 36, pp. 12731-12741.
- Frogley, B & Hill, A 2020, 'Carbyne decorated porphyrins', Dalton Transactions, vol. 49, no. 35, pp. 12390-12400.
- Colebatch, A, Frogley, B, Hill, A et al. 2020, 'Pnictogen-Functionalised C1 Ligands: MC-ARn (n=0, 1, 2, 3)', Chemistry, A European Journal, vol. 27, pp. 23pp.
- Hill, A & Watson, L 2020, 'A heterobimetallic cumulenic μ-carbido complex', Chemical Communications, vol. 56, no. 15, pp. 2356-2359.
- Abernethy, R, Foreman, M, Hill, A et al. 2020, 'Relative hemilabilities of H2B(az)2 (az = pyrazolyl, dimethylpyrazolyl, methimazolyl) chelates in the complexes [M(η-C3H5)(CO)2{H2B(az)2}] (M = Mo, W)', Dalton Transactions, vol. 49, no. 3, pp. 781-796.
- Frogley, B, Hill, A, Sharma, M et al. 2020, 'Semi-bridging silyls as Z-type ligands', Chemical Communications, vol. 56, no. 24, pp. 3532-3535.
- Frogley, B, Hill, A & Seitz, A 2020, 'Bi-and poly(carbyne) functionalised polycyclic aromatics', Chemical Communications, vol. 56, no. 22, pp. 3265-3268.
- Frogley, B, Hill, A & Onn, C 2019, 'Auriferous alkynylselenolatoalkylidynes', Dalton Transactions, vol. 48, no. 31, pp. 11715-11723.
- Frogley, B, Genet, T, Hill, A et al. 2019, 'Alkynylselenolatoalkylidynes (LnM C-Se-C CR) as building blocks for mixed metal/main-group extended frameworks', Dalton Transactions, vol. 48, no. 22, pp. 7632-7643.
- Frogley, B, Hill, A, Onn, C et al. 2019, 'Bi- and Polynuclear Transition-Metal Carbon Tellurides', Angewandte Chemie International Edition, vol. 58, no. 43, pp. 1-5.
- Hill, A & Manzano, R 2019, 'A [C-1 + C-2] route to propargylidyne complexes', Dalton Transactions, vol. 48, no. 19, pp. 6596-6610.
- Frogley, B, Hill, A & Watson, L 2019, 'Bridging selenocarbonyl ligands: an open and shut case', Chemical Communications, vol. 55, no. 96, pp. 14450-14453.
- Manzano, R & Hill, A 2019, 'Propargylidyne and tricarbido complexes', Advances in Organometallic Chemistry, vol. 72, no. 0, pp. 103-171.
- Frogley, B & Hill, A 2019, 'Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes', Chemical Communications, vol. 55, no. 100, pp. 15077-15080.
- Hill, A, Schwich, T & Xiong, Y 2019, '5-Mercaptotetrazolyl-derived metallaboratranes', Dalton Transactions, vol. 48, no. 7, pp. 2367-2376.
- Frogley, B & Hill, A 2019, 'Flexible Platinum(0) Coordination to a Ditungsten Ethanediylidyne', Angewandte Chemie International Edition, vol. 58, no. 24, pp. 8044-8048.
- Colebatch, A, Frogley, B & Hill, A 2019, 'Phosphaisonitrile umpolung - synthesis and reactivity of chloro aminophosphino carbynes', Dalton Transactions, vol. 48, no. 28, pp. 10628-10641.
- Reinholdt, A, Majer, S, Gelardi, R et al 2019, 'An Approach to Carbide-Centered Cluster Complexes', Inorganic Chemistry, vol. 58, no. 8, pp. 4812-4819.
- Hill, A & Manzano, R 2019, 'Pentadiynylidyne and Pentacarbido Complexes', Angewandte Chemie International Edition, vol. 58, no. 22, pp. 7357-7360.
- Ma, C & Hill, A 2019, 'Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes', Dalton Transactions, vol. 48, no. 6, pp. 1976-1992.
- Cade, I, Hill, A & McQueen, C 2019, 'Isoselenocarbonyl complexes', Dalton Transactions, vol. 48, no. 6, pp. 2000-2012.
- Barnett, H & Hill, A 2019, 'Halogenation of A-frame mu-carbido complexes: synthesis of mu(2)-halocarbynes', Chemical Communications, vol. 55, no. 12, pp. 1734-1737.
- Lam, R, McQueen, C, Pernik, I et al 2019, 'Selective formylation or methylation of amines using carbon dioxide catalysed by a rhodium perimidine-based NHC complex', Green Chemistry, vol. 21, no. 3, pp. 538-549.
- Foreman, M, Hill, A, Ma, C et al. 2019, 'Synthesis and ligand substitution reactions of kappa(4)-B,S,S',S''-ruthenaboratranes', Dalton Transactions, vol. 48, no. 1, pp. 209-219.
- Delaney, A, Frogley, B & Hill, A 2019, 'Metal coordination to a dimetallaoctatetrayne', Dalton Transactions, vol. 48, no. 36, pp. 13674-13684.
- Frogley, B, Hill, A & Watson, L 2019, 'New binding modes for CSe: coinage metal coordination to a tungsten selenocarbonyl complex', Dalton Transactions, vol. 48, no. 33, pp. 12598-12606.
- Hill, A & Manzano, R 2019, 'Dimetallapoly-yn-diylidynes: LnM?C?(C?C)x?C?MLn (x=0?4)', Angewandte Chemie International Edition, vol. 58, no. 43, pp. 15354-15357.
- Bartlett, M, Frogley, B, Hill, A et al 2019, 'Hydrogenating an organometallic carbon chain: buten-yn-diyl (CH = 001;CHC C) as a missing link', Dalton Transactions, vol. 48, no. 44, pp. 16534-16554.
- Frogley, B & Hill, A 2019, 'Tungsten-platinum mu-carbido and mu-methylidyne complexes', Chemical Communications, vol. 55, no. 82, pp. 12400-12403.
- Hill, A, Manzano, R & Ward, J 2018, 'Synthesis and reactivity of selenium functionalised allylidynes and propargylidynes', Dalton Transactions, vol. 47, pp. 14621-14629.
- Reinholdt, A, Bendix, J, Hill, A et al. 2018, 'Confluence of disparate carbido chemistries: [WRuAu2(-C)(2)Cl-2(CO)(2)(PCy3)(2)(Tp*)]', Dalton Transactions, vol. 47, no. 42, pp. 14893-14896.
- Hill, A, Ma, C, McQueen, C et al 2018, 'Iridium complexes of perimidine-based N-heterocyclic carbene pincer ligands via aminal C–H activation', Dalton Transactions, vol. 47, no. 5, pp. 1577-1587pp.
- Albayer, M, Corbo, R, Hill, A et al 2018, 'A simple halide and silver-free synthesis of Echavarren's catalyst directly from gold powder', Dalton Transactions, vol. 47, no. 4, pp. 1321-1324.
- Han, Y, Hill, A & Kong, R 2018, 'An unusual alkylidyne homologation', Chemical Communications, vol. 54, no. 18, pp. 2292-2295pp.
- Sung, S, Ang, A, Hill, A et al 2018, 'Bimetallic Complexes of Group 8, 9, and 11 Metals Bridged by RB(NCH2PPh2)2C6H4 (R = H, 4-C6H4X; X = H, Me, F) Ligands', European Journal of Inorganic Chemistry, vol. 2018, no. 24, pp. 2855-2864.
- Frogley, B & Hill, A 2018, 'A complete set of pnictocarbynes: [M( CAPh(2))(CO)(2)(Tp*)] (M = Mo, W; A = N, P, As, Sb, Bi; Tp* = hydrotris(dimethylpyrazolyl)-borate)', Chemical Communications, vol. 54, no. 17, pp. 2126-2129pp.
- Frogley, B & Hill, A 2018, 'Alkynylbis(alkylidynyl)phosphines: {LnM[triple bond, length as m-dash]C}2PC[triple bond, length as m-dash]CR', Chemical Communications, vol. 54, no. 87, pp. 12373-12376pp.
- Frogley, B & Hill, A 2018, 'Bis(alkylidynyl) arsines', Chemical Communications, vol. 54, no. 55, pp. 7649-7652pp.
- Frogley, B, Hill, A, Manzano, R et al 2018, 'Bis(alkylidynyl)tellurides and ditellurides', Chemical Communications, vol. 54, no. 14, pp. 1702-1705pp.
- Hill, A & Manzano, R 2018, 'Synthesis and reactivity of an anionic allenylidene complex', Dalton Transactions, vol. 47, no. 5, pp. 1412-1416pp.
- Barnett, H, Burt, L & Hill, A 2018, 'Simple generation of a dirhodium mu-carbido complex via thiocarbonyl reduction', Dalton Transactions, vol. 47, pp. 9570-9574.
- Reinholdt, A, Hill, A & Bendix, J 2018, 'Synthons for carbide complex chemistry', Chemical Communications, vol. 54, no. 45, pp. 5708-5711.
- Colebatch, A & Hill, A 2017, 'Coordination chemistry of phosphinocarbynes: phosphorus vs. carbyne site selectivity', Dalton Transactions, vol. 46, no. 13, pp. 4355-4365pp.
- Caldwell, L, Hill, A & Willis, A 2017, 'A homologous series of alkynyl chalcoether complexes: [W(η2-iPrEC≡CPh)(CO)2(Tp*)]BF4 (E = O, S, Se, Te; Tp* = hydrotris(dimethylpyrazol-1-yl)borate).', Journal of Organometallic Chemistry, vol. 829, pp. 48-57pp.
- Hill, A & Ward, J 2017, 'Synthetic and structural studies of phosphine coordinated boronium salts', Dalton Transactions, vol. 46, no. 22, pp. 7291-7308pp.
- Hill, A & Kong, R 2017, 'High oxidation state bromocarbyne complexes', Chemical Communications, vol. 53, no. 4, pp. 759-762pp..
- Colebatch, A, Han, Y, Hill, A et al 2017, 'Rearrangement of bis(alkylidynyl)phosphines to phosphaacyls', Chemical Communications, vol. 53, no. 11, pp. 1832-1835 pp.
- Foreman, M, Ma, C, Hill, A et al 2017, 'Dihydrobis(methimazolyl)borato complexes of ruthenium and osmium', Dalton Transactions, vol. 46, pp. 14957-14972.
- Hill, A & Kong, R Y, 2017, 'An anionic nucleophilic d4 carbyne complex', Chemical Communications, vol. 53, no. 12, pp. 2032-2035.
- Colebatch, A & Hill, A 2016, 'Chlorophosphino Carbyne Complexes of Tungsten', Organometallics, vol. 35, no. 13, pp. 2249-2255.
- McQueen, C, Hill, A, Sharma, M et al 2016, 'Synthesis and reactivity of osmium and ruthenium PBP-LXL boryl pincer complexes', Polyhedron, vol. 120, pp. 185-195.
- Caldwell, L, Hill, A, Stranger, R et al 2015, 'Thioxoethenylidene (CCS) as a bridging ligand', Organometallics, vol. 34, no. 1, pp. 328-334.
- Hill, A, Manzano, R, Sharma, M et al 2015, 'Selenoxopropadienylidene (CCCSe) as a bridging ligand', Organometallics, vol. 34, no. 1, pp. 361-365.
- Colebatch, A, Hill, A & Sharma, M 2015, 'Synthesis and Reactivity of Phosphinocarbyne Complexes', Organometallics, vol. 34, no. 11, pp. 2165-2182.
- Hill, A, Ward, J & Xiong, Y 2015, 'Synthesis of a Stable Methylidyne Complex', Organometallics, vol. 34, no. 20, pp. 5057-5064.
- McQueen, C, Hill, A, Ma, C et al 2015, 'Ruthenium and osmium complexes of dihydroperimidine-based N-heterocyclic carbene pincer ligands', Dalton Transactions, vol. 44, no. 47, pp. 20376-20385.
- Hill, A, Stewart, C & Ward, J 2015, 'Organometallic chemistry of ethynyl boronic acid MIDA ester, HCCB(O2CCH2)2NMe', Dalton Transactions, vol. 44, no. 12, pp. 5713-5726.
- Dixon, L, Hill, A, Sinha, A et al 2014, 'N-Heterocyclic silyl pincer ligands', Organometallics, vol. 33, no. 3, pp. 653-658.
- Hill, A & McQueen, C 2014, 'Arrested B-H activation en route to installation of a PBP pincer ligand on ruthenium and osmium', Organometallics, vol. 33, no. 8, pp. 1977-1985.
- Hill, A & McQueen, C 2014, 'Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes', Organometallics, vol. 33, no. 8, pp. 1909-1912.
- Cade, I, Colebatch, A, Hill, A et al 2014, 'Allenylphosphonium complexes of rhodium and iridium', Organometallics, vol. 33, no. 12, pp. 3198-3204.
- Colebatch, A & Hill, A 2014, 'Secondary Phosphinocarbyne and Phosphalsonitrile Complexes', Journal of the American Chemical Society, vol. 136, no. 50, pp. 17442-17445.
- Young, R, Hill, A, Cavigliasso, G et al 2013, '[(μ-C){Re(CO)2(η-C5H5)}2]: A surprisingly simple bimetallic carbido complex', Angewandte Chemie International Edition, vol. 52, no. 13, pp. 3699-3702.
- Borren, E, Hill, A, Shang, R et al 2013, 'A golden ring: molecular gold carbido complexes', Journal of the American Chemical Society, vol. 135, no. 13, pp. 4942-4945.
- Colebatch, A, Cade, I, Hill, A et al 2013, 'η2-Allenyl- and η2-Alkynylphosphonium Complexes of Platinum', Organometallics, vol. 32, no. 17, pp. 4766-4774.
- Hill, A & Fink, M, eds, 2013, Advances in Organometallic Chemistry, Vol. 61, Elsevier Inc., Oxford.
- Hill, A & Fink, M, eds, 2012, Advances in Organometallic Chemistry, Vol. 60, Elsevier Inc., Oxford.
- Hill, A & McQueen, C 2012, 'Novel carbon monochalcogenide coordination mode: [Rh2{μ-SeCMo(CO)2(Tp*)}2(η4-cod)2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)', Organometallics, vol. 31, no. 6, pp. 2482-2485.
- Cade, I & Hill, A 2012, '1,1-Bis(N-methylimidazole)-2-(trimethylsilyl)-1-boracyclohexa-1,4-diene chloride: a stable intermediate or tangent en route to 1-(N-methylimidazole)borabenzene?', Journal of the American Chemical Society, vol. 31, no. 5, pp. 2112-2115.
- Maitlis, P & Hill, A 2012, 'F. Gordon A. Stone: the chemist's chemist', Organometallics, vol. 31, no. 7, pp. 2489-2506.
- Hill, A, Sharma, M & Willis, A 2012, 'Heterodinuclear bridging carbido and phosphoniocarbyne complexes', Organometallics, vol. 31, no. 7, pp. 2538-2542.
- Young, R, Lawes, D, Hill, A et al 2012, 'Observation of a Tungsten Alkane sigma-Complex Showing Selective Binding of Methyl Groups Using FTIR and NMR Spectroscopies', Journal of the American Chemical Society, vol. 134, no. 20, pp. 8294-8297.
- Hill, A & Shang, R 2012, 'Boratocarbyne complexes: Li[Mo{â?¡CB(OMe)3}(CO)2{HB(pzMe2)3}] and [K(18-crown-6)][Mo(â?¡CBF2OMe)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl)', Organometallics, vol. 31, no. 13, pp. 4635-4638.
- Willis, A, Hill, A, Vafazadeh, R et al 2012, 'Synthesis and structural studies of mono- and dinuclear Cu(II) complexes with an ONO donor Schiff base ligand: Self-assembly and sulfato-bridged', Polyhedron, vol. 48, no. 1, pp. 51-57.
- Hill, A & McQueen, C 2012, 'Dihydroperimidine-derived N-heterocyclic pincer carbene complexes via double C-H activation', Organometallics, vol. 31, no. 23, pp. 8051-8054.
- Farmer, J, Man, W, Fox, M et al 2012, 'Syntheses, structures and redox properties of tris(pyrazolyl)borate-capped ruthenium vinyl complexes', Journal of Organometallic Chemistry, vol. 721, pp. 173-185.
- Cordiner, R, Hill, A, Shang, R et al. 2011, 'Group 14 substituted carbyne complexes - an almost complete set: [Mo(≡CAPh3)(CO)2(Tp*)] (Tp* = hydrotris(dimethylpyrazolyl)borate; A = Si, Ge, Sn, Pb but A ≠C).', Organometallics, vol. 30, no. 1, pp. 139-144.
- Hill, A & Fink, M, eds, 2011, Advances in Organometallic Chemistry, Vol. 59, Elsevier Inc., Oxford.
- Brendler, E, Wachtler, E, Heine, T et al 2011, 'Stannylene or metallastanna(IV)ocane: a matter of formalism', Angewandte Chemie International Edition, vol. 50, no. 20, pp. 4696-4700.
- Hill, A, Shang, R & Willis, A 2011, 'Borylcarbyne complexes: [Mo(â?¡CBR2)(CO)2{HB(pzMe2)3}] (BR2 = B(NMe2)2, BO2C6H4; pz = pyrazol-1-yl)', Organometallics, vol. 30, no. 12, pp. 3237-3241.
- Hill, A 2011, 'F. Gordon A. Stone (1925-2011)', Angewandte Chemie International Edition, vol. 50, no. 44, pp. 10284-10285.
- Cade, I & Hill, A 2011, '1-Borabenzonitrile (B-cyanoboratabenzene)', Dalton Transactions, vol. 40, no. 40, pp. 10563-10567.
- Young, R, Hill, A, Hillier, W et al 2011, 'Transition metal-alkane sigma-complexes with oxygen donor co-ligands', Journal of the American Chemical Society, vol. 133, no. 35, pp. 13806-13809.
- Hill, A, Niess, B, Schultz, M et al 2010, 'Organometallic macrocyclic chemistry. 8: an unusual metallacycle derived from phosphine-alkynyl thioether coupling', Organometallics, vol. 29, no. 23, pp. 6488-6492.
- Caldwell, L, Hill, A, Hulkes, A et al 2010, 'Alkynyl selenolate complexes of iron, nickel, and molybdenum.', Organometallics, vol. 29, no. 23, pp. 6350-6358.
- Hill, A & Fink, M, eds, 2010, Advances In Organometallic Chemistry, Vol. 58, Elsevier, USA.
- Hill, A, Colebatch, A, Cordiner, R et al. 2010, 'The odd bit of carbon', Comments on Inorganic Chemistry, vol. 31, no. 3-4, pp. 121-129.
- Wagler, J, Heine, T & Hill, A 2010, 'Poly(methimazolyl)silanes: Syntheses and Molecular Structures', Organometallics, vol. 29, no. 21, pp. 5607-5613.
- Colebatch, A, Hill, A, Shang, R et al. 2010, 'Synthesis of a thiocarbamoyl alkylidyne complex and caveats associated with the use of [Mo(CLi)(CO)2(Tp*)] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate)', Organometallics, vol. 29, no. 23, pp. 6482-6487.
- Hill, A & Fink, M, eds, 2008, Advances in Organometallic Chemistry, Vol. 57, Elsevier Inc., Oxford.
- Hill, A, Smith, M, Tshabang, N et al 2010, 'Bimetallic Dihydrobis(methimazolyl)borate Coordination: Structure [Mo2{μ2-H2B(mt)2}(CO)7][Au2(μ2-H2B(mt)2}](PEt3)2] (mt = methimazoly', Organometallics, vol. 29, no. 2, pp. 473-477.
- Anderson, S, Cook, D & Hill, A 2010, 'A transition-metal alkylidyne complex', in J. Derek Woollins (ed.), Inorganic Experiments (3rd ed), Wiley-VCH Verlag GMBH, Weinheim, pp. 369-371.
- Hill, A, Neumann, H & Wagler, J 2010, 'Bis(methimazolyl)silyl Complexes of Ruthenium', Organometallics, vol. 29, no. 4, pp. 1026-1031.
- Hill, A & Woollins, J 2010, 'Preparation of [Bu4N][B3H8] and the Formation of RuH[B3H8](CO)(PPh3)2', in J. Derek Woollins (ed.), Inorganic Experiments (3rd ed), Wiley-VCH Verlag GMBH, Weinheim, pp. 405-408.
- Hill, A, Lee, S, Park, J et al 2010, 'Analogies between Metallaboratranes, Triboronates, and Boron Pincer Ligand Complexes', Organometallics, vol. 29, no. 21, pp. 5661-5669.
- Crossley, I, Hill, A & Willis, A 2010, 'Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls', Organometallics, vol. 29, no. 2, pp. 326-336.
- Caldwell, L, Cordiner, R, Hill, A et al 2010, 'A Bridging Selenoacyl Complex via Alkynylselenolatoalkylidyne Rearrangement', Organometallics, vol. 29, no. 7, pp. 1526-1529.
- Cade, I, Hill, A, Kampfe, A et al. 2010, 'Five-Coordinate Hydrido-Ruthenium(II) Complexes Featuring N-Heterocyclic Silylene and Carbene Ligands', Organometallics, vol. 29, no. 18, pp. 4012-4017.
- Brendler, E, Heine, T, Hill, A et al. 2009, 'A pentacoordinate chlorotrimethylsilane derivative: a very polar snapshot of a Nucleophilic Substitution and its Influence on 29Si Solid State NMR Properties', Zeitschrift fuer Anorganische und Allgemeine Chemie (ZAAC), vol. 635, no. 9-10, pp. 1300-1305.
- Dewhurst, R, Hill, A & Willis, A 2009, 'Iridium tricarbido complexes via transmetallation with tricarbidomercurials', Dalton Transactions, vol. 2009 advance article, no. 18, pp. 3384-3387.
- Cordiner, R, Hill, A & Wagler, J 2009, 'Reactions of [Ru(CO)2(PPh3)3] with Alkynylphosphonium Salts: Phosphaallenylidene vs Phosphonioacetylide Coordination', Organometallics, vol. 28, no. 16, pp. 4880-4885.
- Ang, W, Cordiner, R, Hill, A et al 2009, 'Reactions of [Ru(CO)2(PPh3)3] with alkynylphosphonium salts: a phosphinoallene complex', Organometallics, vol. 28, no. 18, pp. 5568-5574.
- Abernethy, R, Hill, A, Smith, M et al 2009, 'Boron Functionalization of Bis(pyrazolyl)borate Ligands: Molecular Structures of [RuX(PPh3)2{(MeO)2B(pz)2}] (X = H, Cl; pz = pyrazol-1-yl)', Organometallics, vol. 28, no. 21, pp. 6152-6159.
- Cordiner, R, Gugger, P, Hill, A et al 2009, 'Phosphino and Phosphonito Carbyne Complexes: [Mo(â?¡CX)(CO)2{HB(pzMe2)3}] (X = PPh2, P(:O)(OEt)2; pz = Pyrazol-1-yl).', Organometallics, vol. 28, no. 23, pp. 6632-6635.
- Cade, I, Hill, A & McQueen, C 2009, 'Iridium-Molybdenum Carbido Complex via C-Se Activation of a Selenocarbonyl Ligand:(μ-Se2)[Ir2{C≡Mo(CO)2(Tp*)}2(CO)2(PPh3)2] (Tp*= hydrotris(dimethylpyrazolyl)borate)', Organometallics, vol. 28, no. 23, pp. 6639-6641.
- Dewhurst, R, Hill, A & Willis, A 2009, 'The Interplay of Bis(tricarbido) and Dimetallaoctatetrayne Complexes of Platinum', Organometallics, vol. 28, no. 16, pp. 4735-4740.
- Colebatch, A, Cordiner, R, Hill, A et al. 2009, 'A Bis-Carbyne (Ethanediylidyne) Complex via the Catalytic Demercuration of a Mercury Bis(carbido) Complex', Organometallics, vol. 28, no. 15, pp. 4394-4399.
- Abernethy, R, Hill, A, Tshabang, N et al 2009, 'On the nature of "RuCl(dmso)2{HB(mt)3}" (mt = methimazolyl)', Organometallics, vol. 28, no. 2, pp. 488-492.
- Cade, I, Hill, A, Tshabang, N et al 2009, 'Bimetallic Dihydrobis(methimazolyl)borate Coordination: Molecular Structure [Mo2Au{μ2-H2B(mt)2}(PPh3)(CO)7] (mt = methimazolyl)', Organometallics, vol. 28, no. 4, pp. 1143-1147.
- Foley, N, Abernethy, R, Gunnoe, T et al 2009, 'Chlorination of Boron on a Ruthenium-Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)2Cl', Organometallics, vol. 28, no. 1, pp. 374-377.
- Hill, A, Smith, M & Wagler, J 2008, 'Near linear Ta-H-B geometry: [TaCl2(η-C5Me5){κ3H,S,S'-H2B(methimazolyl)2}]', Organometallics, vol. 27, no. 9, pp. 2137-2140.
- Cordiner, R, Hill, A & Wagler, J 2008, 'Facile generation of Lithiocarbyne Complexes: [M(=CLi)(CO)2{HB(pzMe2)3}] (M = Mo, W; pz = Pyrazol-1-yl)', Organometallics, vol. 27, no. 20, pp. 5177-5179.
- Cade, I, Hill, A & Wagler, J 2008, 'Diels-Alder Dimerization of a Boracyclohexadiene', Organometallics, vol. 27, no. 19, pp. 4844-4846.
- Green, J, Hector, A, Hill, A et al 2008, 'Synthetic and Computational Studies of Thiocarbonyl/Ï?-Organyl Coupling Reactions', Organometallics, vol. 27, no. 21, pp. 5548-5558.
- Brendler, E, Hill, A & Wagler, J 2008, 'A donor-stabilized silanethione or a Si-substituted N-heterocyclic platinum carbene?', Chemistry, A European Journal, vol. 14, no. 36, pp. 11300-11304.
- Cordiner, R, Hill, A & Wagler, J 2008, 'Reactions of [Mo(â?¡CBr)(CO)2{HB(pzMe2)3}] (pz = pyrazol-1-yl) with Amines: Synthesis of Amino, Pyridinium, and Thiolato Carbyne Complexes', Organometallics, vol. 27, no. 17, pp. 4532-4540.
- Abernethy, R, Foreman, M, Hill, A et al 2008, 'Poly(methimazolyl)borato Nitrosyl Complexes of Molybdenum and Tungsten', Organometallics, vol. 27, no. 17, pp. 4455-4463.
- Wagler, J & Hill, A 2008, 'Ring Opening of Organosilicon-Substituted Benzoxazolinone: A Convenient Route to Chelating Ureato and Carbamido Ligands', Organometallics, vol. 27, no. 24, pp. 6579-6586.
- Wagler, J, Hill, A & Heine, T 2008, 'Palladastannatrane - a PdII→SnIV Dative Bond', European Journal of Inorganic Chemistry, no. 27, pp. 4225-4229.
- West, R, Hill, A & Fink, M, eds, 2008, Advances in Organometallic Chemistry, Vol. 55, Academic Press, San Diego.
- West, R, Hill, A & Fink, M, eds, 2008, Advances in Organometallic Chemistry, Vol. 56, Academic Press, San Diego.
- Wagler, J & Hill, A 2008, '7-Azaindol-7-ylborate: A Novel Bidentate N^BH3 Chelating Ligand', Organometallics, vol. 27, no. 10, pp. 2350-2353.
- Caldwell, L, Hill, A, Wagler, J et al 2008, 'Isoselenocarbonyls via acetylenic C-Se activation', Dalton Transactions, vol. 2008/27, pp. 3538-3541.
- Crossley, I & Hill, A 2008, 'Unlocking the metallaboratrane cage: reversible B-H activation in platinaboratranes', Dalton Transactions, vol. 2008/2, pp. 201-203.
- Crossley, I, Hill, A & Willis, A 2008, 'Retention of Pt→B bonding in oxidative addition reactions of the platinaboratrane [Pt(PPh3{B(mt)3}](Pt→B)10 (mt = Methimazolyl)', Organometallics, vol. 27, no. 3, pp. 312-315.
- Crossley, I, Foreman, M, Hill, A et al. 2008, 'Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ruâ??B)8 and [Ru(CO)(CNR){B(mt)3}](Ruâ??B)8 (mt = methimazolyl, R = tBu, C6H3Me2', Organometallics, vol. 27, no. 3, pp. 381-386.
- Caldwell, L, Hill, A, Rae, A et al. 2008, 'Alkynylselenolatoalkylidynes: [Mo(≡CSeC≡CR)(CO)2{HB(pzMe2)3}] (R = CMe3, SiMe3; pzMe2 = 3,5-Dimethylpyrazol-1-yl)', Organometallics, vol. 27, no. 3, pp. 341-345.
- Cowley, A, Hector, A, Hill, A et al 2007, 'Synthesis and Reactions of Five-Coordinate Mono- and Binuclear Thiocarbonyl-Alkenyl and Thioacyl Complexes of Ruthenium(II)', Organometallics, vol. 26, no. 25, pp. 6114-6125.
- Wagler, J & Hill, A 2007, 'Templated Rearrangement of Silylated Benzoxazolin-2-ones: A Novel Tridentate (ONO)2- Chelating Ligand System', Organometallics, vol. 26, no. 15, pp. 3630-3632.
- Hill, A & Smith, M 2007, 'Organometallic Tantalum Tris(methimazolyl)borato Complexes: [Ta(η2-RC�CR)Cl2{HB(mt)3}] (R = Ph, Et; mt = methimazolyl)', Organometallics, vol. 26, no. 18, pp. 4688-4691.
- Hill, A, Tshabang, N & Willis, A 2007, 'Poly(methimazolyl)borate Alkyne Complexes of Molybdenum and Tungsten', European Journal of Inorganic Chemistry, vol. 2007, no. 24, pp. 3781-3785.
- Hill, A, Rae, A, Schultz, M et al. 2007, 'Bis(alkynyl), Metallacyclopentadiene, and Diphenylbutadiyne Complexes of Ruthenium', Organometallics, vol. 26, no. 6, pp. 1325-1338.
- Hill, A & Smith, M 2007, 'A homoleptic hydrotris(methimazolyl)borate complex of titanium', Dalton Transactions, vol. 31, pp. 3363-3364.
- Hill, A & Smith, M 2007, 'Cyclooctatetraene Poly(azolyl)borate Complexes of Zirconium: [Zr(κ2-L)Cl(η-C8H8)] (L = H2B(pz)2, HB(pzMe2)3, H2B(mt)2; pz = Pyrazolyl, mt = Methimaz', Organometallics, vol. 26, no. 16, pp. 3900-3903.
- Crossley, I, Hill, A & Willis, A 2007, 'Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide', Organometallics, vol. 26, no. 16, pp. 3891-3895.
- Hill, A 2006, 'An unambiguous electron-counting notation for metallaboratranes', Organometallics, vol. 25, no. 20, pp. 4741-4743.
- Dewhurst, R, Hill, A & Smith, M 2006, 'Hazards associated with Bis(alkynyl)mercurials', Organometallics, vol. 25, no. 9, pp. 2388-2389.
- Crossley, I, Hill, A, Humphrey, E et al. 2006, 'A less carbocentric view of agostic interactions: the complexes [Rh(η4-cod){H2A(mt)2}] (A = B, C+; mt = Methimazolyl).', Organometallics, vol. 25, no. 9, pp. 2242-2247.
- West, R & Hill, A, eds, 2006, Advances in Organometallic Chemistry, vol 54, Academic Press, London, UK.
- Hill, A & Smith, M 2006, 'Dihydrobis(methimazolyl)borate and methimazolyl complexes of titanium', Dalton Transactions, vol. 1, pp. 28-30.
- Dewhurst, R, Hansen, A, Hill, A et al 2006, 'Templated synthesis and intact coordination of a diorganotriselenane: [RuCl2(PPh3){κ3-Se,N,N'-Se(mtSe)2}] (mtSe = selenomethimazolyl)', Organometallics, vol. 25, no. 25, pp. 5843-5846.
- Crossley, I, Hill, A & Willis, A 2006, 'Metallaboratranes: tris(methimazolyl)borane complexes of rhodium(I)', Organometallics, vol. 25, no. 1, pp. 289-299.
- Hill, A 2005, 'Protagonists in chemistry', Inorganica Chimica Acta, vol. 358, no. 5, pp. 1343-1344.
- Abernethy, R, Hill, A, Neumann, H et al 2005, 'Poly(azolyl) chelate chemistry 14.[1] κ2-S,S vs κ3-H,S,S-H2B(mt)2 (mt = methimazolyl)borate coordination in the complex [W(CO){H2B(mt)2}2]', Inorganica Chimica Acta, vol. 358, no. 5, pp. 1605-1613.
- Dewhurst, R, Hill, A & Smith, M 2005, 'Neutral and anionic tricarbido complexes of gold(I)', Organometallics, vol. 24, no. 23, pp. 5576-5580.
- Hill, A, Rae, A & Smith, M 2005, 'Niobium and tantalum tris(methimazolyl)borate complexes [M(=NC6H3iPr2-2,6)Cl2{HB(mt)3}] (M = Nb, Ta; mt = Methimazolyl)', Inorganic Chemistry, vol. 44, no. 21, pp. 7316-7318.
- Crossley, I, Hill, A & Willis, A 2005, 'Poly(methimazolyl)borate complexes of platinum', Organometallics, vol. 24, no. 21, pp. 4889-4892.
- Dewhurst, R, Hill, A & Smith, M 2005, 'Regioselective Dimetallapolycarbyl Hydrometalation', Organometallics, vol. 24, no. 26, pp. 6295-6297.
- Hill, A, Tocher, D, White, A et al 2005, 'Thiocarbamoyl complexes of ruthenium(II), rhodium(III), and iridium(III)', Organometallics, vol. 24, no. 22, pp. 5342-5355.
- Foreman, M, Hill, A, Smith, M et al 2005, 'Novel heterobimetallic coordination of the H2B(mt)2 ligand: the complex [Mo(SnMe2Cl)(CO)3{μ-S:κ3-H,S,S-H2B(mt)2}] (mt = methimazolyl)', Organometallics, vol. 24, no. 22, pp. 5224-5226.
- Dewhurst, R, Hill, A & Willis, A 2005, 'Stoichiometric and catalytic demercuration of bis(tricarbido)mercurials: The first dimetallaoctatetraynes', Organometallics, vol. 24, no. 13, pp. 3043-3046.
- West, R & Hill, A, eds, 2005, Advances in Organometallic Chemistry, Vol. 52, Academic Press, San Diego.
- Crossley, I, Hill, A, Humphrey, E et al. 2005, 'The first bimetallic metallaboratrane: [Rh2{B(mt)3}2{κ2-S,S-HB(mt)3}]Cl and its synthesis from the fluxional rhodaboratrane salt [Rh{B(mt)3}(η4-C8H12, Organometallics, vol. 24, no. 16, pp. 4083-4086.
- Dewhurst, R, Hill, A, Rae, A et al. 2005, 'Reactions of bis(tricarbido)mercurials and dimetallaoctatetraynes with [Ru(CO)2(PPh3)3]: scission of a Csp-Csp single bond', Organometallics, vol. 24, no. 20, pp. 4703-4706.
- Crossley, I, Hill, A & Willis, A 2005, 'Formation of metallaboratranes: the missing link. The first iridaboratranes, [IrH(CO)(PPh3){κ3-B,S,S-B(mt)2R}](Ir→B) (mt = methimazolyl, R = mt, H)', Organometallics, vol. 24, no. 6, pp. 1062-1064.
- Hill, A & Smith, M 2005, 'Novel poly(methimazolyl)borate complexes of niobium(V) and tantalum(V)', Chemical Communications, vol. 2005/14, pp. 1920-1922.
- Maitlis, P & Hill, A 2005, 'An interview with Peter Maitlis and a selection of highlights from Gordon Stones research by Anthony Hill', Inorganica Chimica Acta, vol. 358, no. 5, pp. 1345-1357.
- Caldwell, L, Hill, A & Willis, A 2005, 'Selenoaroyl complexes of molybdenum', Chemical Communications, vol. 2005/20, pp. 2615-2617.
- Crossley, I, Foreman, M, Hill, A et al. 2005, 'The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh→B) (mt = methimazolyl)', Chemical Communications, vol. 2005/2, pp. 221-223.
- Hill, A, Schultz, M & Willis, A 2005, 'Facile two-step construction of a novel tetrathiamacrotricycle', Organometallics, vol. 24, no. 9, pp. 2027-2029.
- Bartlett, M, Hill, A & Smith, M 2005, 'A Bimetallic Complex Spanned by the C4H Ligand: Synthesis of [Cl(CO)2L2RuC≡CCH=C=RuL2(η-C5H5)PF6 (L = PPh3)', Organometallics, vol. 24, no. 24, pp. 5795-5798.
- Hill, A & West, R, eds, 2005, Advances in Organometallic Chemistry, Vol. 53, Academic Press, San Diego, USA.
- Dewhurst, R, Hill, A & Willis, A 2004, 'Bi- and tetranuclear tricarbido complexes: μ,σ:σ' and μ,σ:σ':π ⊥ coordination of bridging C3 ligands', Organometallics, vol. 23, no. 25, pp. 5903-5906.
- Crossley, I & Hill, A 2004, 'Di- and zerovalent platinaboratranes: The first pentacoordinate d10 platinum(0) complex', Organometallics, vol. 23, no. 24, pp. 5656-5658.
- Hill, A, Schultz, M & Willis, A 2004, 'Reactions of ruthenium(0) phosphine complexes with diphenylacetylene', Organometallics, vol. 23, no. 24, pp. 5729-5736.
- Dewhurst, R, Hill, A & Willis, A 2004, 'A mercury bis(tricarbido) complex: [Hg{C≡C�C≡W(CO)2Tp}2-(dmso)4](dmso)2(Tp = hydrotrispyrazolylborate)', Chemical Communications, vol. N/A, no. 24, pp. 2826-2827.
- Hulkes, A, Hill, A, Nasir, B et al 2004, 'Reactions of μ-alkylidyne complexes with tellurium. Telluroacyl versus μ-telluride formation', Organometallics, vol. 23, no. 4, pp. 679-686.
- Hill, A, Malget, J, White, A et al 2004, 'Dihydrobis(pyrazolyl)borate alkylidyne complexes of tungsten', European Journal of Inorganic Chemistry, vol. N/A, no. 4, pp. 818-828.
- Dewhurst, R, Hill, A & Smith, M 2004, 'Heterobimetallic C3 complexes through silylpropargylidyne desilylation', Angewandte Chemie International Edition, vol. 43, no. 4, pp. 476-478.
- Dewhurst, R, Hill, A & Willis, A 2004, 'A bis(tricarbido) complex of iridium and tungsten: [IrH(C≡CC≡W(CO)2{HB(pz)3})2(CO)(PPh3)2]', Organometallics, vol. 23, no. 8, pp. 1646-1648.
- Crossley, I, Hill, A, Humphrey, E et al. 2004, 'Caveats for poly(methimazolyl)borate chemistry: the novel inorganic heterocycles [H2C(mt)2BR2]Cl (mt = methimazolyl; BR2 = BH2, BH(mt), 9�BBN)', Chemical Communications, vol. N/A, no. 16, pp. 1878-1879.
- Anderson, S, Cook, D, Hill, A et al 2004, 'Reactions of tungsten alkylidynes with thionyl chloride', Organometallics, vol. 23, no. 11, pp. 2552-2557.
- Foreman, M, Hill, A, White, A et al 2004, 'Polyazolyl chelate chemistry. 13. An osmaboratrane', Organometallics, vol. 23, no. 4, pp. 913-916.
- Anderson, S, Berridge, T, Hill, A et al 2004, 'Dihapto carbamoyl (carboxamide) complexes of iron(II)', Organometallics, vol. 23, no. 11, pp. 2686-2693.
- Hill, A, Rae, A, Schultz, M et al. 2004, 'Organometallic macrocyclic chemistry. 6. Chelate-assisted macrocyclization of 4,7,10-trithiatrideca-2,11-diyne', Organometallics, vol. 23, no. 1, pp. 81-85.
- Caldwell, L, Edwards, A, Hill, A et al 2003, 'Rhodium-induced fragmentation and rearrangement of 4,7,10-trithiatrideca-2,11-diyne', Organometallics, vol. 22, no. 12, pp. 2531-2534.
- Foreman, M, Hill, A, White, A et al 2003, 'Hydrotris-(methimazolyl)borato alkylidyne complexes of tungsten', Organometallics, vol. 22, no. 19, pp. 3831-3840.
- Foreman, M, Hill, A, Owen, G et al 2003, 'Polyazolyl chelate chemistry. 12. An unusual mode of coordination for the hydrotris(methimazolyl)borato ligand', Organometallics, vol. 22, no. 22, pp. 4446-4450.
- Cook, D & Hill, A 2003, 'Metallathiirenes. 4. Thioaroyl complexes of molybdenum(II) and tungsten(II)', Organometallics, vol. 22, no. 17, pp. 3502-3512.
- Foreman, M, Hill, A, Tshabang, N et al 2003, 'Metallathiirenes. 5. Bis- and tris(methimazolyl)borato thiocarbamoyl complexes of molybdenum(II)', Organometallics, vol. 22, no. 26, pp. 5593-5596.
- Anderson, S, Cook, D & Hill, A 2003, 'A transition-metal alkylidyne complex', in Woollins, J Derek (ed.), Inorganic Experiments (2nd ed), Wiley-VCH Verlag GMBH, Weinheim, pp. 268-270.
- Hill, A & Woollins, J 2003, 'Preparation of [Bu4N]{B3H8] and the formation of RuH[B3H8](PPh3)2', in Woollins, J Derek (ed.), Inorganic Experiments (2nd ed), Wiley-VCH Verlag GMBH, Weinheim, pp. 271-274.
- Hill, A & Wilton-Ely, J 2002, 'Chlorothiocarbonyl-bis(triphenylphosphine) iridium(I) [IrCl(CS)(PPh3)2].', in Dimitri Coucouvanis (ed.), Inorganic Syntheses, Wiley-VCH Verlag GMBH, New York, pp. 244-245.
- Hill, A & Wilton-Ely, J 2002, 'Chlorohydro-tris(pyrazol-1-yl)borato-bis(triphenylphosphine)ruthenium(II) {RuCl[�3-HB(pz)3]PPh3)2} (pz = pyrazol-1-yl)*.', in Dimitri Coucouvanis (ed.), Inorganic Syntheses, Wiley-VCH Verlag GMBH, New York, pp. 206-208.
- Anderson, S, Cook, D & Hill, A 2001, 'Metallathiirenes. 3. Thiocarbamoyl and alkoxythiocarbonyl complexes of molybdenum(II) and tungsten(II)', Organometallics, vol. 20, no. 12, pp. 2468-2476.
Projects and Grants
Grants information is drawn from ARIES. To add or update Projects or Grants information please contact your College Research Office.
- Boryl Pincers and Beyond: Taming Borometallic Chemistry (Primary Investigator)
- Bimetallic Carbidos: Hard-Wiring a Single Atom of Carbon (Primary Investigator)
- Heteroatomic Organometallic Molecular Wires (Primary Investigator)
- Flow Reactor Chemical Synthesis Facility (Secondary Investigator)
- Borametallacycles: Confluence of Metallacycle and Boracycle Chemistries (Primary Investigator)
- Multinuclear 700 MHz NMR Spectrometer for Advanced Molecular Analysis (Secondary Investigator)
- A DIFFRACTOMETER FOR SMALL MOLECULE STRUCTURAL ELUCIDATION BY CRYSTALLOGRAPHIC ANALYSIS (Primary Investigator)
- Boron and silicon based pincer ligands for environmentally responsible catalysis (Primary Investigator)
- One coordinate carbon and boron: Universal progenitor ligands (Primary Investigator)
- An Integrated Syntheic and NMR Spectroscopic Study of Photochemical Organometallic Bond Activation (Secondary Investigator)
- Understanding and Harnessing the Unique and Curious Metal Boron Bond: Unlocking the Metallaboratrane (Primary Investigator)
